Hydrochloric Acid → 6,6-Dimethyl-4-(trichloromethyl)-3-oxabicyclo[3.1.0]hexan-2-ol

HRID 825275Notes

Reaction equation

HRID 825275 reaction equation
[CH2:2]([Al+:3][CH2:4][CH:5]([CH3:6])[CH3:7])[CH:8]([CH3:9])[CH3:10].[CH3:11][C:12]1([CH3:23])[CH:13]2[CH:14]([C:19]([Cl:20])([Cl:21])[Cl:22])[O:15][C:16](=[O:18])[CH:17]12.[CH3:25][c:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1.[ClH:24].[H-:1]>>[CH3:11][C:12]1([CH3:23])[CH:13]2[CH:14]([C:19]([Cl:20])([Cl:21])[Cl:22])[O:15][CH:16]([OH:18])[CH:17]12

Participants

6

Reactant 5

HCID 313Hydrochloric AcidHCID 1140TolueneHCID 166653HydrideHCID 125252184-Trichloromethyl-6,6-dimethyl-2-oxo-3-oxabicyclo[3.1.0]hexaneHCID 16686348Bis(2-methylpropyl)alumanylium

Product 1

HCID 212840346,6-Dimethyl-4-(trichloromethyl)-3-oxabicyclo[3.1.0]hexan-2-ol

Sources & evidence

ORD record
ord-93cac0e199664228a3a81a068adea127
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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