Dichloromethane → 4-(2'-Methoxy-biphenyl-4-yloxymethyl)-5-methyl-furan-2-carboxylic acid methyl ester

HRID 827230Notes

Reaction equation

HRID 827230 reaction equation
[Br:28][c:29]1[c:30]([O:35][CH3:36])[cH:31][cH:32][cH:33][cH:34]1.[C:37](=[O:38])([O-:39])[O-:40].[CH3:1][O:2][C:3](=[O:4])[c:5]1[o:6][c:7]([CH3:27])[c:8]([CH2:10][O:11][c:12]2[cH:13][cH:14][c:15]([B:18]3[O:19][C:20]([CH3:21])([CH3:22])[C:23]([CH3:24])([CH3:25])[O:26]3)[cH:16][cH:17]2)[cH:9]1.[Cl:43][CH2:44][Cl:45].[Cs+:41].[Cs+:42].[O:46]1[CH2:47][CH2:48][O:49][CH2:50][CH2:51]1>>[CH3:1][O:2][C:3](=[O:4])[c:5]1[o:6][c:7]([CH3:27])[c:8]([CH2:10][O:11][c:12]2[cH:13][cH:14][c:15](-[c:29]3[c:30]([O:35][CH3:36])[cH:31][cH:32][cH:33][cH:34]3)[cH:16][cH:17]2)[cH:9]1

Participants

7

Reactant 6

HCID 6344DichloromethaneHCID 113582-BromoanisoleHCID 19660Carbonate IonHCID 312751,4-DioxaneHCID 104967Cesium cation2×HCID 588241625-Methyl-4-[4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenoxymethyl]-furan-2-carboxylic acid methyl ester

Product 1

HCID 588241584-(2'-Methoxy-biphenyl-4-yloxymethyl)-5-methyl-furan-2-carboxylic acid methyl ester

Sources & evidence

ORD record
ord-0f0a102d1e78404babf2fa5c134b76c7
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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