Chloride → 3,3-Dichloro-1-(2,6-dichloro-5-fluoro-3-pyridinyl)-2-propen-1-one

HRID 827333Notes

Reaction equation

HRID 827333 reaction equation
[Al+3:14].[C:17](=[CH2:18])([Cl:19])[Cl:20].[Cl-:13].[Cl-:15].[Cl-:16].[Cl:1][c:2]1[c:3]([C:4](=[O:5])[Cl:6])[cH:7][c:8]([F:12])[c:9]([Cl:11])[n:10]1.[Cl:21][CH2:22][Cl:23]>>[Cl:1][c:2]1[c:3]([C:4](=[O:5])[CH:18]=[C:17]([Cl:19])[Cl:20])[cH:7][c:8]([F:12])[c:9]([Cl:11])[n:10]1

Participants

6

Reactant 5

HCID 312Chloride3×HCID 6344DichloromethaneHCID 6366Vinylidene chlorideHCID 104727Aluminum CationHCID 27336662,6-Dichloro-5-fluoro-3-pyridinecarbonyl chloride

Product 1

HCID 219481323,3-Dichloro-1-(2,6-dichloro-5-fluoro-3-pyridinyl)-2-propen-1-one

Sources & evidence

ORD record
ord-e4e129f7a9504f4cbae0037361dd91ea
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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