Bromide ion → methyl 11-methyl-6H-pyrido[4,3-b]carbazole-5-carboxylate

HRID 828842Notes

Reaction equation

HRID 828842 reaction equation
[Br-:2].[CH3:50][OH:51].[Cl:46][CH:47]([Cl:48])[Cl:49].[N+:3]([c:4]1[cH:5][cH:6][c:7]([CH2:8][n+:11]2[cH:12][c:13]3[c:14]([c:15]([C:27](=[O:28])[O:29][CH3:30])[c:16]4[nH:17][c:18]5[cH:19][cH:20][cH:21][cH:22][c:23]5[c:24]4[c:25]3[CH3:26])[cH:31][cH:32]2)[cH:9][cH:10]1)([O-:33])=[O:34].[N:35]([c:36]1[cH:37][cH:38][c:39]([N:40]([CH3:41])[CH3:42])[cH:43][cH:44]1)=[O:45].[Na:1]>>[n:11]1[cH:12][c:13]2[c:14]([c:15]([C:27](=[O:28])[O:29][CH3:30])[c:16]3[nH:17][c:18]4[cH:19][cH:20][cH:21][cH:22][c:23]4[c:24]3[c:25]2[CH3:26])[cH:31][cH:32]1

Participants

7

Reactant 6

HCID 259Bromide ionHCID 887MethanolHCID 6212ChloroformHCID 8749N,N-dimethyl-4-nitrosoanilineHCID 5360545SodiumHCID 13808961methyl 11-methyl-2-[(4-nitrophenyl)methyl]-6H-pyrido[4,3-b]carbazol-2-ium-5-carboxylate

Product 1

HCID 13808962methyl 11-methyl-6H-pyrido[4,3-b]carbazole-5-carboxylate

Sources & evidence

ORD record
ord-3b09a03a3c1e4403a8e5933072325b0d
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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