Toluene → Iodide Ion

HRID 829880Notes

Reaction equation

HRID 829880 reaction equation
[CH3:30][c:31]1[cH:32][cH:33][cH:34][cH:35][cH:36]1.[I:20][CH2:21][CH2:22][CH:23]([CH2:24][C:25](=[O:26])[O:27][CH3:28])[CH3:29].[c:1]1([P:7]([c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)[c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)[cH:2][cH:3][cH:4][cH:5][cH:6]1>>[I-:20].[c:1]1([P+:7]([c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)([c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)[CH2:21][CH2:22][CH:23]([CH2:24][C:25](=[O:26])[O:27][CH3:28])[CH3:29])[cH:2][cH:3][cH:4][cH:5][cH:6]1

Participants

5

Reactant 3

HCID 1140TolueneHCID 11776TriphenylphosphineHCID 19767765Methyl 5-iodo-3-methylpentanoate

Product 2

HCID 30165Iodide IonHCID 19767828(5-Methoxy-3-methyl-5-oxopentyl)-triphenylphosphanium

Sources & evidence

ORD record
ord-8e894f7203ae48068e23b25df8c86bd1
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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