Methanol → (2-t-Butoxycarbonylaminoethyl)carbamic acid p-nitrobenzyl ester

HRID 830873Notes

Reaction equation

HRID 830873 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6]([NH:7][CH2:8][CH2:9][N:10]=[N+:11]=[N-:12])=[O:13].[CH2:37]([Cl:38])[Cl:39].[CH3:28][CH2:29][N:30]([CH2:31][CH3:32])[CH2:33][CH3:34].[CH3:35][OH:36].[N+:14](=[O:15])([O-:16])[c:17]1[cH:18][cH:19][c:20]([CH2:21][O:22][C:23](=[O:24])[Cl:25])[cH:26][cH:27]1.[OH-:40].[OH-:42].[Pd+2:41]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6]([NH:7][CH2:8][CH2:9][NH:10][C:23]([O:22][CH2:21][c:20]1[cH:19][cH:18][c:17]([N+:14](=[O:15])[O-:16])[cH:27][cH:26]1)=[O:24])=[O:13]

Participants

8

Reactant 7

HCID 887MethanolHCID 961Hydroxide2×HCID 6344DichloromethaneHCID 8471TriethylamineHCID 782054-Nitrobenzyl chloroformateHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 22323692tert-Butyl (2-azidoethyl)carbamate

Product 1

HCID 69543921(2-t-Butoxycarbonylaminoethyl)carbamic acid p-nitrobenzyl ester

Sources & evidence

ORD record
ord-1d6135b438214fd8b347a329b3dca748
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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