Sodium ion → 6'-Bromo-4-hydroxyspiro[cyclohexane-1,2'-inden]-1'(3'H)-one

HRID 831574Notes

Reaction equation

HRID 831574 reaction equation
[BH4-:18].[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:15]([cH:16]1)[C:14](=[O:17])[C:7]1([CH2:6]2)[CH2:8][CH2:9][C:10](=[O:13])[CH2:11][CH2:12]1.[CH2:20]1[O:21][CH2:22][CH2:23][CH2:24]1.[Na+:19]>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:15]([cH:16]1)[C:14](=[O:17])[C:7]1([CH2:6]2)[CH2:8][CH2:9][CH:10]([OH:13])[CH2:11][CH2:12]1

Participants

5

Reactant 4

HCID 923Sodium ionHCID 8028TetrahydrofuranHCID 28123BorohydrideHCID 581972056'-Bromospiro[cyclohexane-1,2'-indene]-1',4(3'H)-dione

Product 1

HCID 581970336'-Bromo-4-hydroxyspiro[cyclohexane-1,2'-inden]-1'(3'H)-one

Sources & evidence

ORD record
ord-a948f1c11fd14ae998b23c8caad9efd3
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…