Acetate → 2-Iodo-6-methyl-2'-methylsulfinylbenzanilide

HRID 831889Notes

Reaction equation

HRID 831889 reaction equation
[C:31]([O-:32])(=[O:33])[CH3:34].[C:36]([O-:37])(=[O:38])[CH3:39].[CH3:1][c:2]1[c:3]([C:4](=[O:5])[NH:6][c:7]2[c:8]([S:13](=[O:14])[CH3:15])[cH:9][cH:10][cH:11][cH:12]2)[cH:16][cH:17][cH:18][cH:19]1.[CH3:40][N:41]([CH3:42])[C:43](=[O:44])[CH3:45].[I:20][N:21]1[C:22]([CH3:23])([CH3:24])[C:25](=[O:26])[N:27]([I:28])[C:29]1=[O:30].[Pd+2:35]>>[CH3:1][c:2]1[c:3]([C:4](=[O:5])[NH:6][c:7]2[c:8]([S:13](=[O:14])[CH3:15])[cH:9][cH:10][cH:11][cH:12]2)[c:16]([I:20])[cH:17][cH:18][cH:19]1

Participants

6

Reactant 5

HCID 175Acetate2×HCID 31374DimethylacetamideHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 2005341,3-Diiodo-5,5-dimethylimidazolidine-2,4-dioneHCID 220662302-Methyl-2'-methylsulfinylbenzanilide

Product 1

HCID 120105972-Iodo-6-methyl-2'-methylsulfinylbenzanilide

Sources & evidence

ORD record
ord-09a94f87f2b14f018f07854286aaa89c
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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