Potassium Cation → 5-[2-tert-butyl-4-(hydroxymethyl)-5-methyl-phenyl]sulfanyl-2-[2-(2-furyl)ethyl]-4-hydroxy-2-isopropyl-3H-pyran-6-one

HRID 834012Notes

Reaction equation

HRID 834012 reaction equation
[C:19]([CH3:20])([CH3:21])([CH3:22])[c:23]1[c:24]([S:32][S:33]([c:34]2[cH:35][cH:36][c:37]([CH3:38])[cH:39][cH:40]2)(=[O:41])=[O:42])[cH:25][c:26]([CH3:31])[c:27]([CH2:29][OH:30])[cH:28]1.[C:43](=[O:44])([O-:45])[O-:46].[K+:47].[K+:48].[O:49]=[CH:50][N:51]([CH3:52])[CH3:53].[o:1]1[c:2]([CH2:6][CH2:7][C:8]2([CH:16]([CH3:17])[CH3:18])[CH2:9][C:10]([OH:15])=[CH:11][C:12](=[O:14])[O:13]2)[cH:3][cH:4][cH:5]1>>[o:1]1[c:2]([CH2:6][CH2:7][C:8]2([CH:16]([CH3:17])[CH3:18])[CH2:9][C:10]([OH:15])=[C:11]([S:32][c:24]3[c:23]([C:19]([CH3:20])([CH3:21])[CH3:22])[cH:28][c:27]([CH2:29][OH:30])[c:26]([CH3:31])[cH:25]3)[C:12](=[O:14])[O:13]2)[cH:3][cH:4][cH:5]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 19660Carbonate IonHCID 10499026S-[2-Tert-butyl-4-(hydroxymethyl)-5-methylphenyl] 4-methylbenzenesulfonothioateHCID 547051606-(2-Furan-2-yl-ethyl)-4-hydroxy-6-isopropyl-5,6-dihydro-pyran-2-one

Product 1

HCID 546770515-[2-tert-butyl-4-(hydroxymethyl)-5-methyl-phenyl]sulfanyl-2-[2-(2-furyl)ethyl]-4-hydroxy-2-isopropyl-3H-pyran-6-one

Sources & evidence

ORD record
ord-1cce181c70fe44a3bfce39bc349805da
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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