Chloride → 7-Fluoro-2,3-dihydrobenzo[b][1,4]dioxine-6-carbaldehyde

HRID 837783Notes

Reaction equation

HRID 837783 reaction equation
[CH3:12][O:13][CH:14]([Cl:15])[Cl:16].[Cl-:17].[Cl-:18].[Cl-:19].[Cl-:20].[F:1][c:2]1[cH:3][c:4]2[c:5]([cH:10][cH:11]1)[O:6][CH2:7][CH2:8][O:9]2.[Ti+4:21]>>[F:1][c:2]1[cH:3][c:4]2[c:5]([cH:10][c:11]1[CH:12]=[O:13])[O:6][CH2:7][CH2:8][O:9]2

Participants

5

Reactant 4

HCID 312Chloride4×HCID 21004Methane, dichloromethoxy-HCID 114942Titanium cation (4+)HCID 124645456-Fluoro-2,3-dihydro-1,4-benzodioxine

Product 1

HCID 146448837-Fluoro-2,3-dihydrobenzo[b][1,4]dioxine-6-carbaldehyde

Sources & evidence

ORD record
ord-29a6f6fda6404208ab592047aa26d81e
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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