Potassium Cation → 5-Bromo-1-(2,6-dichlorophenyl)-3,4-dihydro-7-methoxy-2(1H)-quinolinone

HRID 838577Notes

Reaction equation

HRID 838577 reaction equation
[Cl:1][c:2]1[c:3]([NH:9][C:10]([CH2:11][CH2:12][c:13]2[c:14]([Br:22])[cH:15][c:16]([O:20][CH3:21])[cH:17][c:18]2[Br:19])=[O:23])[c:4]([Cl:8])[cH:5][cH:6][cH:7]1.[Cu:36][I:37].[K+:24].[K+:25].[O-:26][C:27]([O-:28])=[O:29].[cH:30]1[cH:31][cH:32][n:33][cH:34][cH:35]1>>[Cl:1][c:2]1[c:3]([N:9]2[C:10](=[O:23])[CH2:11][CH2:12][c:13]3[c:14]([Br:22])[cH:15][c:16]([O:20][CH3:21])[cH:17][c:18]32)[c:4]([Cl:8])[cH:5][cH:6][cH:7]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 1049PyridineHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 22647977N-(2,6-Dichlorophenyl)-3-(2,6-dibromo-4-methoxyphenyl)-propionamide

Product 1

HCID 226479975-Bromo-1-(2,6-dichlorophenyl)-3,4-dihydro-7-methoxy-2(1H)-quinolinone

Sources & evidence

ORD record
ord-54c06e4727a548a5a6850bbd3d934b60
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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