HRID839322

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7397

p-Toluenesulfonyl chloride

C7H7ClO2S

结构：O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.O=C1C=CCC1CCCCCO.[Br-].[Br-]

HCID178526340

未命名化合物

PRODUCTS

生成物

结构：Cc1ccc(S(=O)(=O)OCCCCCC2=CCCC2=O)cc1.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]

HCID178427726

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1049

Pyridine

C5H5N

PROCEDURE

实验过程

Treatment of 2-(hydroxypentyl)-2-cyclopentenone methoxime (Example 25) with p-toluenesulfonyl chloride in pyridine in the manner described in Example 18 gives a colorless oil. IR (film) 1600, 1190, 1180, 1050, 885 cm-1.

WORKUP

后处理

customgives a colorless oil

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-3e100fe9238942b3a0f27e9de0d5617a
来源数据集: uspto-grants-1978_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04094896
来源说明: uspto-grants-1978_06

反应 SMILES

[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]1[C:11](=[O:12])[CH:10]=[CH:9][CH2:8]1.[CH:13]1[C:14](/[CH:29]=[N:30]/[OH:31])=[CH:15][CH:16]=[N+:17]([CH2:19][N+:20]2[CH:25]=[CH:24][C:23](/[CH:26]=[N:27]/[OH:28])=[CH:22][CH:21]=2)[CH:18]=1.[Br-:32].[Br-].[C:34]1([CH3:44])[CH:39]=[CH:38][C:37]([S:40](Cl)(=[O:42])=[O:41])=[CH:36][CH:35]=1>N1C=CC=CC=1>[C:34]1([CH3:44])[CH:39]=[CH:38][C:37]([S:40]([O:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]2[C:11](=[O:12])[CH2:10][CH2:9][CH:8]=2)(=[O:42])=[O:41])=[CH:36][CH:35]=1.[CH:15]1[C:14](/[CH:29]=[N:30]/[OH:31])=[CH:13][CH:18]=[N+:17]([CH2:19][N+:20]2[CH:21]=[CH:22][C:23](/[CH:26]=[N:27]/[OH:28])=[CH:24][CH:25]=2)[CH:16]=1.[Br-:32].[Br-:32]