Potassium Hydroxide → HCID 12474700, compound

HRID 840084Notes

Reaction equation

HRID 840084 reaction equation
[CH2:1]([C:9]1[CH:10]([C:12]([O:14]CC)=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[OH-].[K+]>CCOCC>[CH2:1]([C:9]1[CH:10]([C:12]([OH:14])=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 22621698Ethyl 2-octylcycloprop-2-ene-1-carboxylate

Product 1

HCID 12474700HCID 12474700, compoundYield 81.5%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Ethyl 2-octylcycloprop-2-ene-1-carboxylate (1.12 g, 5 mmol) and 100 ml of 0.2 N potassium hydroxide were stirred at room temperature for one week. Ether was added and the phases were separated. The aqueous phase was acidified and extracted with methylene chloride. The organic phase was dried over magnesium sulfate and stripped to give 0.8 g of 2-octylcycloprop-2-ene-1-carboxylic acid.

Workup

  1. customthe phases were separated
  2. extractionextracted with methylene chloride
  3. dry with materialThe organic phase was dried over magnesium sulfate

Sources & evidence

ORD record
ord-cf19c3b1ee5b4fdeb74266067d37b03a
Source dataset
uspto-grants-2002_04
Patent number
US06365549B2

Reaction notes

Loading…