HRID840643

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5289077

Methyl (2S)-2-hydroxy-3-phenylpropanoate

C10H12O3

结构：COc1ccc(-c2cc(-c3ccc(-c4c(Cc5ccccc5)oc5ccccc45)cc3)ccc2O)cc1

HCID10672435

未命名化合物

PRODUCTS

生成物

结构：COc1ccc(-c2cc(-c3ccc(-c4c(Cc5ccccc5)oc5ccccc45)cc3)ccc2O[C@@H](Cc2ccccc2)C(=O)O)cc1

HCID9830685

未命名化合物

PROCEDURE

实验过程

The title compound was prepared from 4-(2-benzyl-benzofuran-3-yl)-4″-methoxy-[1,1′;3′,1″]terphenyl-4′-ol, and (S)-(−)-3-phenyllactic acid methyl ester, in substantially the same manner, as described in Example 1, steps g-h , and was obtained as a white solid, mp 73-75° C.; MS m/e 629 (M−H)+;

WORKUP

后处理

customwas obtained as a white solid, mp 73-75° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f37e8fc864304ccfbc40fc52c65b1ffc
来源数据集: uspto-grants-2002_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06369072B2
来源说明: uspto-grants-2002_04

反应 SMILES

[CH2:1]([C:8]1[O:9][C:10]2[CH:37]=[CH:36][CH:35]=[CH:34][C:11]=2[C:12]=1[C:13]1[CH:18]=[CH:17][C:16]([C:19]2[CH:24]=[CH:23][C:22]([OH:25])=[C:21]([C:26]3[CH:31]=[CH:30][C:29]([O:32][CH3:33])=[CH:28][CH:27]=3)[CH:20]=2)=[CH:15][CH:14]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C[O:39][C:40](=[O:50])[C@H:41]([CH2:43][C:44]1[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=1)O>>[CH2:1]([C:8]1[O:9][C:10]2[CH:37]=[CH:36][CH:35]=[CH:34][C:11]=2[C:12]=1[C:13]1[CH:14]=[CH:15][C:16]([C:19]2[CH:24]=[CH:23][C:22]([O:25][C@@H:41]([CH2:43][C:44]3[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=3)[C:40]([OH:50])=[O:39])=[C:21]([C:26]3[CH:27]=[CH:28][C:29]([O:32][CH3:33])=[CH:30][CH:31]=3)[CH:20]=2)=[CH:17][CH:18]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1