HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-amino-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-one → Methyl 6-methyl-6,7-dihydro-5H-benzocycloheptene-8-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-amino-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-one | HCID 266807 | — |
| Reactant | 3-methylthio-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-one | HCID 22620503 | — |
| Reactant | Methyl 2-methylthio-6,7-dihydro-5H-benzocycloheptene-8-carboxylate | HCID 22620567 | — |
| Product | Methyl 6-methyl-6,7-dihydro-5H-benzocycloheptene-8-carboxylate | HCID 22620535 | — |
| Product | Methyl 2-methylthio-6,7-dihydro-5H-benzocycloheptene-8-carboxylate | HCID 22620567 | — |
Reaction Steps
Methyl 2-methylthio-6,7-dihydro-5H-benzocycloheptene-8-carboxylate was synthesized by carrying out reactions according to the methods described in Reference Example 1, (a) to (c), except for using the 3-methylthio-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-one obtained in the above item (b).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06369110B1 |
| Source dataset | uspto-grants-2002_04 |
| ORD ID | ord-c986fc94259648ca83bc5cfcf0a36a83 |
| Source note | uspto-grants-2002_04 |