N-(1-Adamantyl)hydroxylamine → HCID 85045133, compound

HRID 842982Notes

Reaction equation

HRID 842982 reaction equation
[CH:1]([C:3]1[O:7][C:6]([S:8]([OH:11])(=[O:10])=[O:9])=[CH:5][CH:4]=1)=O.[Na].[C:13]12([NH:23][OH:24])[CH2:22][CH:17]3[CH2:18][CH:19]([CH2:21][CH:15]([CH2:16]3)[CH2:14]1)[CH2:20]2>>[C:13]12([N+:23]([O-:24])=[CH:1][C:3]3[O:7][C:6]([S:8]([OH:11])(=[O:10])=[O:9])=[CH:5][CH:4]=3)[CH2:22][CH:17]3[CH2:18][CH:19]([CH2:21][CH:15]([CH2:16]3)[CH2:14]1)[CH2:20]2

Participants

4

Reactant 3

HCID 316867N-(1-Adamantyl)hydroxylamineHCID 27240012-Formylfuran-5-sulfonateHCID 5360545Sodium2×

Product 1

HCID 85045133HCID 85045133, compoundYield 59%

Procedure

Following the procedure of Example 1 above and using 5-formylfuran-2-sulfonic acid, sodium salt hydrate and N-adamantylhydroxylamine, the title compound was prepared in 59% yield as the sodium salt, m.p. 236.9° C. (dec.).

Sources & evidence

ORD record
ord-0e5b027a91164a31bd859ba3b04cda84
Source dataset
uspto-grants-2002_04
Patent number
US06376540B1

Reaction notes

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