Potassium Carbonate → HCID 18522031, compound

HRID 843582Notes

Reaction equation

HRID 843582 reaction equation
[N+:1]([C:4]1[CH:17]=[CH:16][CH:15]=[CH:14][C:5]=1[NH:6][C:7]1[CH:12]=[CH:11][C:10]([NH2:13])=[CH:9][CH:8]=1)([O-:3])=[O:2].Br[C:19]1[S:20][CH:21]=[CH:22][N:23]=1.C(=O)([O-])[O-].[K+].[K+]>O>[N+:1]([C:4]1[CH:17]=[CH:16][CH:15]=[CH:14][C:5]=1[NH:6][C:7]1[CH:8]=[CH:9][C:10]([NH:13][C:19]2[S:20][CH:21]=[CH:22][N:23]=2)=[CH:11][CH:12]=1)([O-:3])=[O:2]

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 764302-BromothiazoleHCID 18522089N~1~-(2-Nitrophenyl)benzene-1,4-diamine

Product 1

HCID 18522031HCID 18522031, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

2-Nitro-N-(4-aminophenyl)aniline (5.0 g, 21.8 mmol), 2-bromothiazole (3.58 g, 21.8 mmol) and potassium carbonate (3.01 g, 21.8 mmol) was stirred at 150° C. for 24 h. Water (250 ml) was added and the mixture was extracted with ethyl acetate (250 ml).

Workup

  1. extractionthe mixture was extracted with ethyl acetate (250 ml)

Sources & evidence

ORD record
ord-ca9d5e99acb1499fa36c6b82bea3f149
Source dataset
uspto-grants-2002_04
Patent number
US06380180B1

Reaction notes

Loading…