HRID844909

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5948

Tributyltin

C12H28Sn

HCID8900

Heptane

C7H16

HCID12225

Ethanol, 2-iodo-

C2H5IO

结构：CC1(C)CC(OC(=O)CCCCCCCCC(=O)OC2CC(C)(C)N(O)C(C)(C)C2)CC(C)(C)N1O

HCID11272241

Bis-(tetramethyl hydroxypiperidinyl) sebacate

C28H52N2O6

HCID21899848

未命名化合物

PRODUCTS

生成物

结构：CC1(C)CC(OC(=O)CCCCCCCCC(=O)OC2CC(C)(C)N(OCCO)C(C)(C)C2)CC(C)(C)N1OCCO

HCID22507665

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID7964

Chlorobenzene

C6H5Cl

PROCEDURE

实验过程

Tributyltin hydride is added dropwise to a solution of 2-iodoethanol and excess bis(1-oxyl-—2,2,6,6-tetramethylpiperidin-4-yl) sebacate in chlorobenzene. The crude reaction mixture is passed through silica gel with heptane and then heptane/ethyl acetate to afford the title compound.

WORKUP

后处理

customThe crude reaction mixture

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d277e1cfdb034ce099522804068642e6
来源数据集: uspto-grants-2002_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06380389B2
来源说明: uspto-grants-2002_04

反应 SMILES

C([SnH](CCCC)CCCC)CCC.I[CH2:15][CH2:16][OH:17].[C:18]([O:42][CH:43]1[CH2:48][C:47]([CH3:50])([CH3:49])[N:46]([OH:51])[C:45]([CH3:53])([CH3:52])[CH2:44]1)(=[O:41])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27]([O:29][CH:30]1[CH2:35][C:34]([CH3:37])([CH3:36])[N:33]([OH:38])[C:32]([CH3:40])([CH3:39])[CH2:31]1)=[O:28].CCCCCCC.CCCCCCC.[C:68](OCC)(=[O:70])[CH3:69]>ClC1C=CC=CC=1>[OH:17][CH2:16][CH2:15][O:38][N:33]1[C:32]([CH3:39])([CH3:40])[CH2:31][CH:30]([O:29][C:27](=[O:28])[CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][C:18]([O:42][CH:43]2[CH2:44][C:45]([CH3:53])([CH3:52])[N:46]([O:51][CH2:69][CH2:68][OH:70])[C:47]([CH3:50])([CH3:49])[CH2:48]2)=[O:41])[CH2:35][C:34]1([CH3:36])[CH3:37]