HCID 13986139, compound → HCID 13986138, compound

HRID 845254Notes

Reaction equation

HRID 845254 reaction equation
[O:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[C:3]([CH:10]([OH:18])[C:11]([O:13][CH2:14][CH2:15][CH2:16][CH3:17])=[O:12])=[CH:2]1.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.[Pb+4]>C1C=CC=CC=1>[O:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[C:3]([C:10](=[O:18])[C:11]([O:13][CH2:14][CH2:15][CH2:16][CH3:17])=[O:12])=[CH:2]1

Participants

4

Reactant 2

HCID 13986139HCID 13986139, compoundHCID 178418268HCID 178418268, compound

Product 1

HCID 13986138HCID 13986138, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

14.9 g of butyl benzofur-3-yl-glycolate and 26.6 of lead tetraacetate are refluxed for 8 hours in 125 ml of absolute benzene. After working up as described in Example 15, 8.7 g (59% of theory) of an oil, boiling point 132°-136° C. (1 Torr), nD20 =1.537, are obtained.

Workup

  1. customnD20 =1.537, are obtained

Sources & evidence

ORD record
ord-15cc508f61fa469eba6a867c06e45bd2
Source dataset
uspto-grants-1988_07
Patent number
US04757085

Reaction notes

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