Hydrazine hydrate (1:1) → HCID 20132475, compound

HRID 845267Notes

Reaction equation

HRID 845267 reaction equation
[CH3:1][C:2]1[NH:3][C:4]([CH3:41])=[C:5]([C:21]([O:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][N:30]2C(=O)C3=CC=CC=C3C2=O)=[O:22])[CH:6]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[N+:18]([O-:20])=[O:19])[C:7]=1[C:8]([O:10][CH3:11])=[O:9].O.NN>>[CH3:1][C:2]1[NH:3][C:4]([CH3:41])=[C:5]([C:21]([O:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][NH2:30])=[O:22])[CH:6]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[N+:18]([O-:20])=[O:19])[C:7]=1[C:8]([O:10][CH3:11])=[O:9]

Participants

3

Reactant 2

HCID 24654Hydrazine hydrate (1:1)HCID 14011676HCID 14011676, compound

Product 1

HCID 20132475HCID 20132475, compound

Procedure

Prepared by a method analogous to that of Example 1(b) from 9.1 g (16 mmol) of 1,4-dihydro-2,6-dimethyl-3-methoxycarbonyl-4-(2-nitrophenyl)-5-(6-phthalimidohexyloxy)carbonyl-pyridine and 2.4 ml (49 mmol) of hydrazine hydrate. 6.2 g (89%) of an orange coloured oil.

Sources & evidence

ORD record
ord-23cc430e18054a518e0951299a6d9136
Source dataset
uspto-grants-1988_07
Patent number
US04757080

Reaction notes

Loading…