HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 2-(2'-nitrobenzylidene)acetoacetate → HCID 20132459, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 2-(2'-nitrobenzylidene)acetoacetate | HCID 787115 | — |
| Reactant | HCID 67903649 | HCID 67903649 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 20132459 | HCID 20132459 | — |
Reaction Steps
13.7 g (55 mmol) of 2-(2-nitrobenzylidene)-acetoacetic acid methyl ester and 16.6 g (55 mmol) of 3-aminocrotonic acid-(4-phthalimido-butyl)ester are boiled in 150 ml of ethanol for 18 hours. The orange yellow oil (28.7 g-98%) obtained after removal of the solvent by evaporation under vacuum is used for further reactions without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04757080 |
| Source dataset | uspto-grants-1988_07 |
| ORD ID | ord-a4feb850124e408295f40ff2f25c4718 |
| Source note | uspto-grants-1988_07 |