3-Phenylprop-2-Enal → 5-(4-Phenyl-1,3-butadienyl)-1,2-dithiol-3-thione

HRID 845740Notes

Reaction equation

HRID 845740 reaction equation
[CH:1](=O)[CH:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH3:11][C:12]1[S:16][S:15][C:14](=[S:17])[CH:13]=1>>[C:4]1([CH:3]=[CH:2][CH:1]=[CH:11][C:12]2[S:16][S:15][C:14](=[S:17])[CH:13]=2)[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Participants

3

Reactant 2

HCID 3073-Phenylprop-2-EnalHCID 1378993H-1,2-Dithiole-3-thione, 5-methyl-

Product 1

HCID 539425735-(4-Phenyl-1,3-butadienyl)-1,2-dithiol-3-thione

Procedure

In the same manner as in Example 1, a corresponding cinnamaldehyde derivative (i.e., 4-chloro-cinnamaldehyde, 4-methoxy-cinnamaldehyde, 4-dimethylamino-cinnamaldehyde, p-methyl-cinnamaldehyde, o-chloro-cinnamaldehyde or m-methyl-cinnamaldehyde) was reacted with 5-methyl-1,2-dithiol-3-thione to prepare the following compounds.

Workup

  1. customto prepare the following compounds

Sources & evidence

ORD record
ord-8da12743090d4d08b19c9191b2d334a4
Source dataset
uspto-grants-1988_07
Patent number
US04760078

Reaction notes

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