HuagongsheHuagongshe Chemistry Print Report · For research reference only
Imidazole → Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Imidazole | HCID 795 | — |
| Reactant | Propargyl alcohol | HCID 7859 | — |
| Reactant | tert-Butyldiphenylchlorosilane | HCID 94078 | — |
| Product | Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)- | HCID 610226 | — |
Reaction Steps
2.9 ml of 2-propyn-1-ol, 15.6 ml of tert-butyldiphenylchlorosilane and 4.1 g of imidazole were reacted in the manner described in Example 14c. Chromatography of the raw product on silica gel [Kieselgel 60 (0.063-0.200 mm)] with petroleum ether/diisopropylether (20:1) yielded 13.3 g of the title compound in the form of crystals melting at 55°-58° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04760087 |
| Source dataset | uspto-grants-1988_07 |
| ORD ID | ord-90496f26a3044947943c12d3bc7703bc |
| Source note | uspto-grants-1988_07 |