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HRID845806

反应详情

EQUATION

反应方程式

HRID 845806 的结构方程式

REACTANTS

反应物

3
结构：c1c[nH]cn1
HCID795

Imidazole

C3H4N2

结构：C#CCO
HCID7859

Propargyl alcohol

C3H4O

结构：CC(C)(C)[Si](Cl)(c1ccccc1)c1ccccc1
HCID94078

Silane, chloro(1,1-dimethylethyl)diphenyl-

C16H19ClSi

PRODUCTS

生成物

1
结构：C#CCO[Si](c1ccccc1)(c1ccccc1)C(C)(C)C
HCID610226

Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)-

C19H22OSi

PROCEDURE

实验过程

2.9 ml of 2-propyn-1-ol, 15.6 ml of tert-butyldiphenylchlorosilane and 4.1 g of imidazole were reacted in the manner described in Example 14c. Chromatography of the raw product on silica gel [Kieselgel 60 (0.063-0.200 mm)] with petroleum ether/diisopropylether (20:1) yielded 13.3 g of the title compound in the form of crystals melting at 55°-58° C.