Sodium ethoxide → HCID 20130691, compound

HRID 845907Notes

Reaction equation

HRID 845907 reaction equation
C([O:3][C:4]([C:6]1[CH2:10][CH2:9][CH2:8][C:7]=1[NH:11][C:12](=[O:28])[NH:13][C:14]1[CH:15]=[CH:16][C:17]([N+:25]([O-:27])=[O:26])=[C:18]([CH:24]=1)[C:19]([O:21][CH2:22][CH3:23])=[O:20])=O)C.CC[O-].[Na+]>C(O)C>[N+:25]([C:17]1[CH:16]=[CH:15][C:14]([N:13]2[C:4](=[O:3])[C:6]3[CH2:10][CH2:9][CH2:8][C:7]=3[NH:11][C:12]2=[O:28])=[CH:24][C:18]=1[C:19]([O:21][CH2:22][CH3:23])=[O:20])([O-:27])=[O:26]

Participants

4

Reactant 2

HCID 2723922Sodium ethoxideHCID 20130595HCID 20130595, compound

Product 1

HCID 20130691HCID 20130691, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

using ethyl 5-{3-[2-(ethoxycarbonyl)-1-cyclopenten-1-yl]ureido}-2-nitrobenzoate with sodium ethylate in ethanol there is obtained ethyl 2-nitro-5-(1,2,4,5,6,7-hexahydro-2,4-dioxo-3H-cyclopenta[d]pyrimidin-3-yl)-benzoate, m.p. 205°-208° C.,

Sources & evidence

ORD record
ord-4937193917354fa5a98b9a8c9f2604bd
Source dataset
uspto-grants-1988_07
Patent number
US04760163

Reaction notes

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