Sodium ethoxide → HCID 20130581, compound

HRID 845931Notes

Reaction equation

HRID 845931 reaction equation
[N+:1]([C:4]1[CH:14]=[CH:13][C:12]([N:15]2[C:20](=[O:21])[C:19]3[CH2:22][CH2:23][CH2:24][C:18]=3[NH:17][C:16]2=[O:25])=[CH:11][C:5]=1[C:6]([O:8][CH2:9][CH3:10])=[O:7])([O-:3])=[O:2].[CH3:26]C[O-].[Na+]>C(O)C>[N+:1]([C:4]1[CH:14]=[CH:13][C:12]([N:15]2[C:20](=[O:21])[C:19]3[CH2:22][CH2:23][CH2:24][C:18]=3[N:17]([CH3:26])[C:16]2=[O:25])=[CH:11][C:5]=1[C:6]([O:8][CH2:9][CH3:10])=[O:7])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 2723922Sodium ethoxideHCID 20130691HCID 20130691, compound

Product 1

HCID 20130581HCID 20130581, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

using ethyl 2-nitro-5-(1,2,4,5,6,7-hexahydro-2,4-dioxo-3H-cyclopenta[d]pyrimidin-3-yl)-benzoate with sodium ethylate in ethanol there is obtained ethyl 2-nitro-5-(1,2,4,5,6,7-hexahydro-1-methyl-2,4-dioxo-3H-cyclopenta[d]pyrimidin-3-yl)-benzoate, m.p. 188°-190° C.,

Sources & evidence

ORD record
ord-30bfb6eeb63a4dfca8d54b7e3c2b80f1
Source dataset
uspto-grants-1988_07
Patent number
US04760163

Reaction notes

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