HCID 67915154, compound → HCID 19883665, compound

HRID 846711Notes

Reaction equation

HRID 846711 reaction equation
[CH3:1][N:2]([CH3:20])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]/[CH:8]=[CH:9]\[C:10]1[CH:19]=[CH:18][C:13]([C:14]([O:16][CH3:17])=[O:15])=[CH:12][CH:11]=1>C(O)C.[Pd]>[CH3:20][N:2]([CH3:1])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]1[CH:11]=[CH:12][C:13]([C:14]([O:16][CH3:17])=[O:15])=[CH:18][CH:19]=1

Participants

4

Reactant 1

HCID 67915154HCID 67915154, compound

Product 1

HCID 19883665HCID 19883665, compoundYield 95.9%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

0.88 g of methyl 4-[(Z)-7-(dimethylamino)-1-heptenyl]benzoate was dissolved in 20 ml of ethanol, 20 mg of 5 percent palladium on carbon were added thereto and the suspension was stirred under hydrogen at normal pressure and room temperature for 2 hours. The reaction mixture was filtered through siliceous earth and the filtrate was evaporated. There was obtained 0.85 g (95%) of methyl 4-[7-(dimethylamino)heptyl]benzoate as a colourless oil.

Workup

  1. filtrationThe reaction mixture was filtered through siliceous earth
  2. customthe filtrate was evaporated

Sources & evidence

ORD record
ord-b280573c05484f0a98e7f1a6eb614c14
Source dataset
uspto-grants-1992_08
Patent number
US05137920

Reaction notes

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