HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Dodecanethiol → Ethyl Acrylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Dodecanethiol | HCID 8195 | — |
| Reactant | Tert-butyl 2-ethyl-2-methylheptaneperoxoate | HCID 71359725 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Ethyl Acrylate | HCID 8821 | — |
| Product | Decyl methacrylate | HCID 18510 | — |
Reaction Steps
350 g of toluene, 135 g of ethyl acrylate, and 15 g of n-decyl methacrylate were polymerized with stirring in a reaction flask at 50°-60° C. under argon with 0.3 g of dodecyl mercaptan as a regulator and 2 g of t-butyl perneodecanoate as initiator. After about 30 minutes of reaction, the mixture was precipitated in methanol and the polymer was dried under vacuum.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05141993 |
| Source dataset | uspto-grants-1992_08 |
| ORD ID | ord-c2b49c75adc9482d84cd3eef32fdd950 |
| Source note | uspto-grants-1992_08 |