HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Butanol → Butoxy(dimethyl)(2-methyl-2-propanyl)silane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | O-Xylene | HCID 7237 | — |
| Reactant | tert-Butyldimethylsilyl chloride | HCID 28928 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | Butoxy(dimethyl)(2-methyl-2-propanyl)silane | HCID 529138 | — |
Reaction Steps
0.1 moles of n-butanol, 0.15 moles of t-butyldimethylchlorosilane and 0.0005 moles of triethylbenzyl ammonium chloride were heated under reflux (77°-106° C.) in 50 ml of p-xylene. After termination of the reaction, excess silylating agent and xylene were distilled off at reduced pressure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05142081 |
| Source dataset | uspto-grants-1992_08 |
| ORD ID | ord-e5d031e0d5d84f549d027f7bca7010c4 |
| Source note | uspto-grants-1992_08 |