1-Butanol → Butoxy(dimethyl)(2-methyl-2-propanyl)silane

HRID 847489Notes

Reaction equation

HRID 847489 reaction equation
[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[C:6]([Si:10]([CH3:13])([CH3:12])Cl)([CH3:9])([CH3:8])[CH3:7].C1(C)C(C)=CC=CC=1>[Cl-].C([N+](CC)(CC)CC1C=CC=CC=1)C.CC1C=CC(C)=CC=1>[CH2:1]([O:5][Si:10]([C:6]([CH3:9])([CH3:8])[CH3:7])([CH3:13])[CH3:12])[CH2:2][CH2:3][CH3:4]

Participants

6

Reactant 3

HCID 2631-ButanolHCID 7237O-XyleneHCID 28928tert-Butyldimethylsilyl chloride

Product 1

HCID 529138Butoxy(dimethyl)(2-methyl-2-propanyl)silane

Reagents, catalysts & solvents 2

HCID 66133Benzyl triethylammonium chlorideCatalystHCID 7809P-XyleneSolvent

Procedure

0.1 moles of n-butanol, 0.15 moles of t-butyldimethylchlorosilane and 0.0005 moles of triethylbenzyl ammonium chloride were heated under reflux (77°-106° C.) in 50 ml of p-xylene. After termination of the reaction, excess silylating agent and xylene were distilled off at reduced pressure.

Workup

  1. distillationwere distilled off at reduced pressure

Sources & evidence

ORD record
ord-e5d031e0d5d84f549d027f7bca7010c4
Source dataset
uspto-grants-1992_08
Patent number
US05142081

Reaction notes

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