Cyclohexene → Hexylcyclohexyldichlorosilane

HRID 848828Notes

Reaction equation

HRID 848828 reaction equation
[CH2:1]([SiH:7]([Cl:9])[Cl:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH:10]1[CH2:15][CH2:14][CH2:13][CH2:12][CH:11]=1>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH2:1]([Si:7]([CH:10]1[CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]1)([Cl:9])[Cl:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

4

Reactant 2

HCID 8079CyclohexeneHCID 92038703Dichloro(hexyl)silane

Product 1

HCID 53776952Hexylcyclohexyldichlorosilane

Reagents, catalysts & solvents 1

HCID 61859Chloroplatinic acidCatalyst

Conditions

Temperature
40 °C

Procedure

This n-hexyldichlorosilane in an amount of 30.5 g (0.165 mol), 17.2 g of cyclohexene (0.21 mol) and 0.05 mol % of chloroplatinic acid (relative to hexyldichlorosilane) were subjected to reaction in a flask with stirring at a temperature of 40° C. for 20 hours. No hexylcyclohexyldichlorosilane was obtained.

Sources & evidence

ORD record
ord-75b96d384b8e4ad5b41733c5a146d1fe
Source dataset
uspto-grants-1981_10
Patent number
US04297499

Reaction notes

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