Benzoyl chloride → HCID 178486250, compound

HRID 849800Notes

Reaction equation

HRID 849800 reaction equation
[C:1]([NH:5][NH:6][PH:7]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1C)=[O:8])([CH3:4])([CH3:3])[CH3:2].[CH2:16](N(CC)CC)C.[C:23](Cl)(=[O:30])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>C(OCC)C.CCCCCC>[C:1]([N:5]([C:23](=[O:30])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)[N:6]([PH:7]([C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)=[O:8])[CH3:16])([CH3:2])([CH3:3])[CH3:4]

Participants

6

Reactant 3

HCID 7412Benzoyl chlorideHCID 8471TriethylamineHCID 178424407HCID 178424407, compound

Product 1

HCID 178486250HCID 178486250, compound

Reagents, catalysts & solvents 2

HCID 3283Diethyl EtherSolventHCID 8058HexaneSolvent

Procedure

N'-t-butyl-N-(methylphenyl)phosphinylhydrazine (0.7 g) and triethylamine (3 ml) were stirred in diethyl ether (30 ml) at room temperature. Slowly, dropwise benzoyl chloride (1.2 g) was added to the reaction mixture. After stirring 1 hour at room temperature, the reaction mixture was diluted with hexane and the solid product filtered off. The white solid melted at 175-178° C.

Workup

  1. filtrationthe solid product filtered off

Sources & evidence

ORD record
ord-5be7e3919852403c9912a3da89e73280
Source dataset
uspto-grants-2000_01
Patent number
US06013836

Reaction notes

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