Methyl nitrite → HCID 86583921, compound

HRID 850264Notes

Reaction equation

HRID 850264 reaction equation
[CH3:1][S:2][C:3]1[CH:4]=[C:5]([CH:9]=[CH:10][C:11]=1[S:12][CH3:13])[CH2:6][C:7]#[N:8].C[O:15][N:16]=O>>[OH:15][N:16]=[C:6]([C:7]#[N:8])[C:5]1[CH:9]=[CH:10][C:11]([S:12][CH3:13])=[C:3]([S:2][CH3:1])[CH:4]=1

Participants

3

Reactant 2

HCID 12231Methyl nitriteHCID 19362515HCID 19362515, compound

Product 1

HCID 86583921HCID 86583921, compoundYield 58.1%

Procedure

According to the method described under 1.1., 34.8 g (0.166 mol) of 3,4-bis(methylthio)benzyl cyanide are reacted with 0.166 mol methylnitrite. After the isolation 23.0 g (58%) α-hydroxyimino-3,4-bis(methylthio)benzyl cyanide are obtained as a brown substance with a melting point of 131-133° C. Elemental analysis: C10H10N2OS2 (238.33)

Sources & evidence

ORD record
ord-2ac8f4f664ff4c5882be8fe0ed743b7f
Source dataset
uspto-grants-2000_01
Patent number
US06017675

Reaction notes

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