HuagongsheHuagongshe Chemistry Print Report · For research reference only
O-Phenylhydroxylamine hydrochloride → methyl (2Z)-2-(furan-2-yl)-2-[1-(phenoxycarbamoyl)cyclopentyl]oxyiminoacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | O-Phenylhydroxylamine hydrochloride | HCID 6365179 | — |
| Reactant | 1-[(Z)-[1-(furan-2-yl)-2-methoxy-2-oxoethylidene]amino]oxycyclopentane-1-carboxylic acid | HCID 88736760 | — |
| Product | methyl (2Z)-2-(furan-2-yl)-2-[1-(phenoxycarbamoyl)cyclopentyl]oxyiminoacetate | HCID 20501531 | 44% |
Reaction Steps
This compound prepared from methyl Z-2-(carboxycyclopent-1-yloxyimino)-2-(fur-2-yl)acetate and phenoxyamine hydrochloride as described in Preparation 7(c), was purified by chromatography on silica gel plates in ethyl acetate-light petroleum b.p. 40°-60° (3:1 v/v). τ(DMSO d6) 2.5-3.1 (phenyl), 7.7-8.1, 8.1-8.5 (cyclopentyl), 2.0, 3.28, 3.02 (furyl), 6.03 (methyl). Yield 44%
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04385177 |
| Source dataset | uspto-grants-1983_05 |
| ORD ID | ord-d1eb09f14e4644afaa2c21b49ac57763 |
| Source note | uspto-grants-1983_05 |