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HRID851681

反应详情

EQUATION

反应方程式

HRID 851681 的结构方程式

REACTANTS

反应物

1
结构：CC(=O)OC[C@H]1O[C@H](SCCC(=O)NCCC[C@H](NC(=O)CCS[C@H]2O[C@H](COC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H]2OC(C)=O)C(=O)O)[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O
HCID86738906

未命名化合物

PRODUCTS

生成物

1
结构：O=C(CCS[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]1O)NCCC[C@H](NC(=O)CCS[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]1O)C(=O)O
HCID57035602

未命名化合物

收率 100%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCN(CC)CC.CO.O
溶剂HCID23434731

未命名化合物

PROCEDURE

实验过程

A solution of 36 (100 mg) in MeOH-H2O-Et3N 5:4:1 (v/v/v, 3 ml) is kept for 3 hours at room temperature, and evaporated to a residue which is put on a Sephadex G-25 column and eluted with water. The desired fractions are combined and lyophilized to give the title compound (65 mg, 100%): NMR (D2O)δ: 5.38 (d, J1,2 =15 Hz), 5.35 (d,J1,2 =1.5 Hz) (H-1), 2.70 (t), 2.63 (t) (SCH2CH2).

WORKUP

后处理

  1. customevaporated to a residue which
  2. washeluted with water