Trimethyl phosphite → HCID 23320145, compound

HRID 851700Notes

Reaction equation

HRID 851700 reaction equation
C[O:2][P:3]([O:6][CH3:7])[O:4][CH3:5].Cl[C:9]([O:11][CH:12]1[CH:19]2[CH2:20][CH:15]3[CH2:16][CH:17]([CH2:21][CH:13]1[CH2:14]3)[CH2:18]2)=[O:10]>>[CH:19]12[CH2:20][CH:15]3[CH2:16][CH:17]([CH2:21][CH:13]([CH2:14]3)[CH:12]1[O:11][C:9]([P:3](=[O:2])([O:6][CH3:7])[O:4][CH3:5])=[O:10])[CH2:18]2

Participants

3

Reactant 2

HCID 8472Trimethyl phosphiteHCID 108785372-adamantyl Chloroformate

Product 1

HCID 23320145HCID 23320145, compound

Procedure

From 1.5 g (12 mmole) of trimethylphosphite and 2.0 g (9.3 mmole) of 2-adamantyl chloroformate. (100°-110° C., 2 hrs). Yield 1.0 g (37%). Bp0.3 160° C.

Workup

  1. custom(100°-110° C., 2 hrs)
  2. customBp0.3 160° C.

Sources & evidence

ORD record
ord-0e0945f353d54d3c983261921c99c2e1
Source dataset
uspto-grants-1983_05
Patent number
US04386081

Reaction notes

Loading…