Trimethyl phosphite → HCID 13077901, compound

HRID 851702Notes

Reaction equation

HRID 851702 reaction equation
C[O:2][P:3]([O:6][CH3:7])[O:4][CH3:5].Cl[C:9]([O:11][C:12]1[CH:17]=[CH:16][C:15]([C:18]([O:20][CH2:21][CH3:22])=[O:19])=[CH:14][CH:13]=1)=[O:10]>>[CH2:21]([O:20][C:18]([C:15]1[CH:16]=[CH:17][C:12]([O:11][C:9]([P:3](=[O:2])([O:6][CH3:7])[O:4][CH3:5])=[O:10])=[CH:13][CH:14]=1)=[O:19])[CH3:22]

Participants

3

Reactant 2

HCID 8472Trimethyl phosphiteHCID 13077891HCID 13077891, compound

Product 1

HCID 13077901HCID 13077901, compound

Procedure

From 16.1 g (0.13 mole) of trimethylphosphite and 22.8 g (0.10 mole) of 4-ethoxycarbonylphenyl chloroformate. (100° C., 3 hours). Yield 26.7 g (88%). Bp0.05 205°-7° C.

Workup

  1. custom(100° C., 3 hours)
  2. customBp0.05 205°-7° C.

Sources & evidence

ORD record
ord-dea8841e77914a1c9c1f8fe3806ad4fd
Source dataset
uspto-grants-1983_05
Patent number
US04386081

Reaction notes

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