m-Chloroperbenzoic acid → HCID 69459136, compound

HRID 852412Notes

Reaction equation

HRID 852412 reaction equation
[CH2:1]([O:3][C:4](=[O:20])[C:5]([O:8][C:9]1[CH:14]=[CH:13][C:12](C(=O)C)=[C:11]([F:18])[C:10]=1[CH3:19])([CH3:7])[CH3:6])[CH3:2].ClC1C=CC=[C:24]([C:28]([O:30]O)=[O:29])C=1>>[CH2:1]([O:3][C:4](=[O:20])[C:5]([O:8][C:9]1[CH:14]=[CH:13][C:12]([O:30][C:28](=[O:29])[CH3:24])=[C:11]([F:18])[C:10]=1[CH3:19])([CH3:6])[CH3:7])[CH3:2]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 69457704HCID 69457704, compound

Product 1

HCID 69459136HCID 69459136, compound

Procedure

In analogy to the procedure described in example 32D], 2-(4-acetyl-3-fluoro-2-methyl-phenoxy)-2-methyl-propionic acid ethyl ester was oxidized with a total of 4.5 equivalent of 3-chloro perbenzoic acid during 6 day to give the title compound as orange semisolid residue.

Sources & evidence

ORD record
ord-2deecc7db4ea4ffaae91fa6fd7e637ad
Source dataset
uspto-grants-2007_08
Patent number
US07253192B2

Reaction notes

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