1,3-Dichloroacetone → HCID 86598513, compound

HRID 854678Notes

Reaction equation

HRID 854678 reaction equation
[CH3:1][O:2][C:3]1[CH:11]=[CH:10][C:6]([C:7]([NH2:9])=[S:8])=[CH:5][CH:4]=1.[Cl:12][CH2:13][C:14]([CH2:16]Cl)=[O:15]>CC(C)=O>[ClH:12].[Cl:12][CH2:13][C:14](=[O:15])[CH2:16][S:8][C:7](=[NH:9])[C:6]1[CH:10]=[CH:11][C:3]([O:2][CH3:1])=[CH:4][CH:5]=1

Participants

4

Reactant 2

HCID 107931,3-DichloroacetoneHCID 7368274-Methoxybenzenecarbothioamide

Product 1

HCID 86598513HCID 86598513, compoundYield 119%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

13.38 g (80.0 mmol) 4-Methoxy-thiobenzamide, 15.23 g (120 mmol) 1,3-dichloroacetone and 400 ml acetone were stirred at room temperature for 3 days. The precipitate was isolated and dried, yielding 21.0 g (quant.) 4-methoxy-thiobenzimidic acid 3-chloro-2-oxo-propyl ester hydrochloride.

Workup

  1. customThe precipitate was isolated
  2. customdried

Sources & evidence

ORD record
ord-ea6ab41a820945ec9d6d3ca7cea9189e
Source dataset
uspto-grants-2007_08
Patent number
US07259262B2

Reaction notes

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