Acrolein → N-(4-Methoxybenzylidene)-4-methylthioaniline

HRID 856819Notes

Reaction equation

HRID 856819 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([CH:9]([NH:12][C:13]2[CH:18]=[CH:17][C:16]([S:19][CH3:20])=[CH:15][CH:14]=2)C#N)=[CH:5][CH:4]=1.C(C=C)=O>>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([CH:9]=[N:12][C:13]2[CH:18]=[CH:17][C:16]([S:19][CH3:20])=[CH:15][CH:14]=2)=[CH:7][CH:8]=1

Participants

3

Reactant 2

HCID 7847AcroleinHCID 21862854alpha-(4-Methoxyphenyl)-alpha-(4-methylthioanilino)acetonitrile

Product 1

HCID 21862760N-(4-Methoxybenzylidene)-4-methylthioaniline

Procedure

Following a procedure similar to that described in Example 21 (iii), but using α-(4-methoxyphenyl)-α-(4-methylthioanilino)acetonitrile [prepared as described in step (ii) above] and acrolein as starting materials, the title compound was obtained as a white powder (yield 9%), melting at 183-184° C.

Sources & evidence

ORD record
ord-5be77a34cfbb4d90af8a382763010306
Source dataset
uspto-grants-2006_12
Patent number
USRE039420E1

Reaction notes

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