Chloroethane → HCID 91202882, compound

HRID 856865Notes

Reaction equation

HRID 856865 reaction equation
[P:1]([O:8][CH2:9][CH3:10])([O:5][CH2:6][CH3:7])[O:2]CC.ClC[C:13]1[C:22]2[C:17](=[CH:18]C=C[CH:21]=2)[CH:16]=[CH:15][CH:14]=1.[CH2:23](Cl)C>>[CH3:23][P:1](=[O:2])([O:5][C:6]1[C:7]2[C:14](=[CH:15][CH:16]=[CH:17][CH:18]=2)[CH:13]=[CH:22][CH:21]=1)[O:8][CH2:9][CH3:10]

Participants

4

Reactant 3

HCID 6337ChloroethaneHCID 68451-ChloromethylnaphthaleneHCID 31215Triethyl phosphite

Product 1

HCID 91202882HCID 91202882, compoundYield 75%

Procedure

A mixture of 8.31 g (50 mmol) triethyl phosphite and 8.83 g (50 mmol) 1-chloromethyl naphthalene was heated for about 30 minutes until the evolution of gas (C2H5Cl) at 200° C. (external temperature) was finished. The reaction mixture was cooled to room temperature, to give 10.38 g NMPA (crude yield, 75%) as colorless oily liquid.

Sources & evidence

ORD record
ord-a13397a714f54be9a663159270a41482
Source dataset
uspto-grants-2006_12
Patent number
US07144614B2

Reaction notes

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