4-Bromothiophenol → 1-Bromo-4-(3-methylbut-2-enylsulphanyl)benzene

HRID 858271Notes

Reaction equation

HRID 858271 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([SH:8])=[CH:4][CH:3]=1.Br[CH2:10][CH:11]=[C:12]([CH3:14])[CH3:13]>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH2:10][CH:11]=[C:12]([CH3:14])[CH3:13])=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 660494-BromothiophenolHCID 700922-Butene, 1-bromo-3-methyl-

Product 1

HCID 150967451-Bromo-4-(3-methylbut-2-enylsulphanyl)benzeneYield 93%

Procedure

In a manner similar to that of Example 34(h), by reaction of 30.00 g (159.0 mmol) of 4-bromo-thiophenol with 26.00 g (175.0 mmol) of 1-bromo-3-methyl-2-butene, 37.40 g (93%) of the expected product are obtained in the form of a yellow oil.

Sources & evidence

ORD record
ord-821253acb6c6473c9f050dc807a5a118
Source dataset
uspto-grants-2006_12
Patent number
US07148245B2

Reaction notes

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