Allyl bromide → HCID 19702699, compound

HRID 861264Notes

Reaction equation

HRID 861264 reaction equation
[OH:1][CH2:2][CH2:3][NH:4][C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1.[CH2:14](Br)[CH:15]=[CH2:16]>CN1CCCC1=O>[CH2:16]([N:4]([CH2:3][CH2:2][OH:1])[C:5]1[CH:6]=[CH:7][C:8]([N+:11]([O-:13])=[O:12])=[CH:9][CH:10]=1)[CH:15]=[CH2:14]

Participants

4

Reactant 2

HCID 7841Allyl bromideHCID 2661542-[(4-nitrophenyl)amino]ethanol

Product 1

HCID 19702699HCID 19702699, compound

Reagents, catalysts & solvents 1

HCID 13387N-methyl-2-pyrrolidoneSolvent

Procedure

N-(2-hydroxyethyl)-4-nitrobenzenamine (9.1 g, 0.05 mol) is treated with allyl bromide in N-methylpyrrolidone, also as subsequently discussed in Example 11, to provide N-allyl-N-(2-hydroxyethyl)-4-nitrobenzenamine.

Sources & evidence

ORD record
ord-3a331c28066c45748e51f2493f64f9aa
Source dataset
uspto-grants-1998_02
Patent number
US05714304

Reaction notes

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