Diethyl Oxalate → HCID 22097060, compound

HRID 861454Notes

Reaction equation

HRID 861454 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([NH2:8])[C:5]([NH2:9])=[CH:4][C:3]=1[N:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1.[C:15](OCC)(=[O:21])[C:16](OCC)=[O:17]>>[Cl:1][C:2]1[CH:7]=[C:6]2[C:5]([NH:9][C:15](=[O:21])[C:16](=[O:17])[NH:8]2)=[CH:4][C:3]=1[N:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1

Participants

3

Reactant 2

HCID 7268Diethyl OxalateHCID 22097227HCID 22097227, compound

Product 1

HCID 22097060HCID 22097060, compound

Procedure

0.6 g (2.9 mmol) of N-(2-chloro-4,5-diaminophenyl)pyrrole and 32 g (221 mmol) of diethyl oxalate were refluxed for 3 hours. The reaction mixture was cooled and then the crude product was filtered off and washed with petroleum ether.

Workup

  1. temperatureThe reaction mixture was cooled
  2. filtrationthe crude product was filtered off
  3. washwashed with petroleum ether

Sources & evidence

ORD record
ord-840b98d3c36f42e6b1356c01c19d7564
Source dataset
uspto-grants-1998_02
Patent number
US05714489

Reaction notes

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