Diphenyl carbonate → Methyl Benzoate

HRID 861674Notes

Reaction equation

HRID 861674 reaction equation
C(=O)([O-])O[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:11](=O)([O:14]C1C=CC=CC=1)[O:12][CH3:13].C(=O)(OC1C=CC=CC=1)OC1C=CC=CC=1>>[C:11]([O:12][CH3:13])(=[O:14])[C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][CH:8]=1

Participants

4

Reactant 3

HCID 7597Diphenyl carbonateHCID 139482Carbonic acid, methyl phenyl esterHCID 21923897HCID 21923897, compound

Product 1

HCID 7150Methyl BenzoateYield 41%

Procedure

The same procedures as in Example 1 were used, except that the reaction temperature of the phenyl carbonate preparation step was 210° C. As a result, the yield of methyl phenyl carbonate was 17%, and the yield of diphenyl carbonate was 24%. Furthermore, at the same time, methyl benzoate was produced as a by-product with a yield of 41% (the yield was based on phenyl benzoate).

Workup

  1. customwas 210° C

Sources & evidence

ORD record
ord-580544ef8b13418a9ccf8ef58f1394e1
Source dataset
uspto-grants-1998_02
Patent number
US05714627

Reaction notes

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