Ethanol → HCID 19701563, compound

HRID 862109Notes

Reaction equation

HRID 862109 reaction equation
[CH2:1]([OH:3])[CH3:2].[C:4]([O:8]/[N:9]=[C:10](\[C:19]1[C:24]([CH2:25][O:26][CH3:27])=[CH:23][CH:22]=[CH:21][N:20]=1)/[C:11]1[CH:16]=[C:15]([Br:17])[CH:14]=[CH:13][C:12]=1[OH:18])([CH3:7])([CH3:6])[CH3:5]>C(O)CC>[C:4]([O:8]/[N:9]=[C:10](\[C:19]1[C:24]([CH2:25][O:26][CH3:27])=[CH:23][CH:22]=[CH:21][N:20]=1)/[C:11]1[CH:16]=[C:15]([Br:17])[CH:14]=[CH:13][C:12]=1[OH:18])([CH3:7])([CH3:6])[CH3:5].[Br:17][C:15]1[CH:14]=[CH:13][C:12]([OH:18])=[C:2]([CH:16]=1)[C:1]([C:19]1[C:24]([CH2:25][O:26][CH3:27])=[CH:23][CH:22]=[CH:21][N:20]=1)=[O:3]

Participants

5

Reactant 2

HCID 702EthanolHCID 136463730HCID 136463730, compound

Product 2

HCID 19701563HCID 19701563, compoundHCID 136463730HCID 136463730, compound

Reagents, catalysts & solvents 1

HCID 10311-PropanolSolvent

Procedure

Using ethanol, in place of n-propanol in Example 17, (Z)-2-(5-bromo-2-hydroxybenzoyl)-3-methoxymethylpyridine O-t-butyloxime (60 mg) (Compound 180) was produced from 2-(5-bromo-2-hydroxybenzoyl)-3-methoxymethylpyridine (80 mg).

Sources & evidence

ORD record
ord-d476a2c9c955453898e53243da40c824
Source dataset
uspto-grants-1998_02
Patent number
US05716971

Reaction notes

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