Chloride → HCID 19699085, compound

HRID 863027Notes

Reaction equation

HRID 863027 reaction equation
[Cl:1][C:2]1[CH:23]=[C:22]([N+:24]([O-])=O)[CH:21]=[CH:20][C:3]=1[C:4]([N:6]1[CH2:12][C:11]2[S:13][CH:14]=[CH:15][C:10]=2[CH2:9][C:8]2[N:16]=[CH:17][CH:18]=[CH:19][C:7]1=2)=[O:5].[Cl-]>C(O)C>[Cl:1][C:2]1[CH:23]=[C:22]([NH2:24])[CH:21]=[CH:20][C:3]=1[C:4]([N:6]1[CH2:12][C:11]2[S:13][CH:14]=[CH:15][C:10]=2[CH2:9][C:8]2[N:16]=[CH:17][CH:18]=[CH:19][C:7]1=2)=[O:5]

Participants

4

Reactant 2

HCID 312ChlorideHCID 19699123HCID 19699123, compound

Product 1

HCID 19699085HCID 19699085, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

As described for Reference Example 204 5-(2-chloro-4-nitrobenzoyl)-6,10-dihydro-5H-pyrido[3,2-b]-thieno[3,2-e]azepine is reduced with stannus chloride (SnCl2) in ethanol to give the product as a solid.

Sources & evidence

ORD record
ord-8bc6d43890d34ae081173de944e18e1c
Source dataset
uspto-grants-1998_02
Patent number
US05719278

Reaction notes

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