HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfuryl chloride → HCID 70044133, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfuryl chloride | HCID 24648 | — |
| Reactant | HCID 70046405 | HCID 70046405 | — |
| Product | HCID 70044133 | HCID 70044133 | 51% |
Reaction Steps
The 0.07 g sample of material obtained in the early fractions from the chromatographic separation described above in Preparation 16A consisting predominantly of 2-phenylthiomethyl-4,7-dimethylsaccharin was reacted with 0.05 ml of sulfuryl chloride in MDC and the product recrystallized from cyclohexane-ethyl acetate to give 20 mg (51%) of 2-chloromethyl-4,7-dimethylsaccharin, mp 107°-108° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05563163 |
| Source dataset | uspto-grants-1996_10 |
| ORD ID | ord-f2cbc3686b4a4cc9b317e1fb57c8ac93 |
| Source note | uspto-grants-1996_10 |