Methanol → HCID 54223459, compound

HRID 865402Notes

Reaction equation

HRID 865402 reaction equation
CO.[N+:3]([C:6]1[CH:21]=[CH:20][C:9]([O:10][CH2:11][C:12]([CH3:19])=[CH:13][CH2:14]CC([O-])=O)=[CH:8][CH:7]=1)([O-:5])=[O:4].C(=O)([O-])[O-:23].[K+].[K+]>O>[N+:3]([C:6]1[CH:21]=[CH:20][C:9]([O:10][CH2:11][C:12]([CH3:19])=[CH:13][CH2:14][OH:23])=[CH:8][CH:7]=1)([O-:5])=[O:4]

Participants

5

Reactant 3

HCID 887MethanolHCID 11430Potassium CarbonateHCID 67746492HCID 67746492, compound

Product 1

HCID 54223459HCID 54223459, compoundYield 176.5%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

Into methanol (1,200 ml) and water (400 ml) were dissolved 120 g (0.25 mol) of [4-(p-nitrophenoxy)-3-methyl-2-butenyl]acetate. With stirring at room temperatures, 40 g (0.29 mol) of potassium carbonate were added therein, and stirred for one hour. The reaction liquid was added into water and extracted with ethyl acetate. After the organic layer was washed with water and dried, the solvent was distilled off, whereby 98.5 g of the title compound were obtained. (Yield: 98.5%)

Workup

  1. additionwere added
  2. customThe reaction liquid
  3. extractionextracted with ethyl acetate
  4. washAfter the organic layer was washed with water
  5. customdried
  6. distillationthe solvent was distilled off

Sources & evidence

ORD record
ord-e6df1e1c71f848b0abacbb44b3459621
Source dataset
uspto-grants-1996_10
Patent number
US05565586

Reaction notes

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