Nitric Acid → HCID 10176704, compound

HRID 865490Notes

Reaction equation

HRID 865490 reaction equation
[F:1][C:2]1[C:7]([F:8])=[C:6]([F:9])[CH:5]=[CH:4][C:3]=1[Cl:10].S(=O)(=O)(O)O.[N+:16]([O-])([OH:18])=[O:17]>>[Cl:10][C:3]1[C:2]([F:1])=[C:7]([F:8])[C:6]([F:9])=[CH:5][C:4]=1[N+:16]([O-:18])=[O:17]

Participants

4

Reactant 3

HCID 944Nitric AcidHCID 1118Sulfuric Acid2×HCID 142097Benzene, 1-chloro-2,3,4-trifluoro-

Product 1

HCID 10176704HCID 10176704, compound

Procedure

If 0.15 mol of 2,3,4-trifluorochlorobenzene in 50 g of 100% strength sulfuric acid as diluent is used and nitration is carried out with 30.5 g (0.165 mol) of mixed acid prepared from 68.8% by weight of 100% strength H2SO4 and 31.2% by weight of 100% strength HNO3 at from 5° to 12° C., then reaction is complete after metered addition for 1 hour followed by stirring for an additional hour. The result is essentially the same.

Workup

  1. customreaction
  2. additionafter metered addition for 1 hour

Sources & evidence

ORD record
ord-dbd063c3d7ad4b13885891df3738961a
Source dataset
uspto-grants-1996_10
Patent number
US05565612

Reaction notes

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